Bacteriochlorophyll a


Catalog No. size PriceQuantity
M7002-2 2mg solid $886
M7002-10 10mg solid $3,544

Description

Cas:17499-98-8

Product Information

Bacteriochlorophyll a is a Bacteriochlorophyll from Rhodopseudomonas sphaeroides. Bacteriochlorophylls a, b, and g are bacteriochlorins, meaning their molecules have a bacteriochlorin macrocycle ring with two reduced pyrrole rings (B and D). Bacteriochlorophylls c, d, e, and f are chlorins, meaning their molecules have a chlorin macrocycle ring with one reduced pyrrole ring (D).

 

Chemical Formula: C55H74MgN4O6

 

Exact Mass: 910.5459

 

Molecular Weight: 911.524

 

Elemental Analysis: C, 72.47; H, 8.18; Mg, 2.67; N, 6.15; O, 10.53

 

Synonym: 

 

Bacteriochlorophyll a

Bacteriochlorophyll

C11242

Bacteriochlorophyll from Rhodopseudomonas sphaeroides

 

Chemical Name:

magnesium;methyl(3R,11R,12R,21S,22S)-16-acetyl-11-ethyl-12,17,21,26-tetramethyl-4-oxo-22-[3-oxo-3-[(E,7R,11R)-3,7,11,15-tetramethylhexadec-2-enoxy]propyl]-23,25-diaza-7,24-diazanidahexacyclo[18.2.1.15,8.110,13.115,18.02,6]hexacosa-1(23),2(6),5(26),8,10(25),13,15,17,19-nonaene-3-carboxylate

 

InChi Key: 

DSJXIQQMORJERS-AGGZHOMASA-M

 

InChi Code: InChI=1S/C55H75N4O6.Mg/c1-13-39-34(7)41-29-46-48(38(11)60)36(9)43(57-46)27-42-35(8)40(52(58-42)50-51(55(63)64-12)54(62)49-37(10)44(59-53(49)50)28-45(39)56-41)23-24-47(61)65-26-25-33(6)22-16-21-32(5)20-15-19-31(4)18-14-17-30(2)3;/h25,27-32,34-35,39-40,51H,13-24,26H2,1-12H3,(H-,56,57,58,59,60,62);/q-1;+2/p-1/b33-25+;/t31-,32-,34-,35+,39-,40+,51-;/m1./s1

 

Smiles Code:

CC[C@@H]1[C@H](C2=CC3=C(C(=C([N-]3)C=C4[C@H]([C@@H](C(=N4)C5=C6C(=C(C(=CC1=N2)[N-]6)C)C(=O)[C@@H]5C(=O)OC)CCC(=O)OC/C=C(\C)/CCC[C@H](C)CCC[C@H](C)CCCC(C)C)C)C)C(=O)C)C.[Mg+2]

 

 

Technical Data:

 

Appearance: Solid powder

Purity: >98% (or refer to the Certificate of Analysis)

Shipping Condition: Shipped under ambient temperature as non-hazardous chemical. This product is stable enough for a few weeks during ordinary shipping and time spent in Customs.

Storage Condition: Dry, dark and at 0 - 4 C for short term (days to weeks) or -20 C for long term (months to years).

Solubility: Soluble in DMSO

Shelf Life: >3 years if stored properly

Drug Formulation: This drug may be formulated in DMSO

Stock Solution Storage: 0 - 4 C for short term (days to weeks), or -20 C for long term (months).

HS Tariff Code: 2934.99.9001

 

 

References

 

1, Pankratov TA, Grouzdev DS, Patutina EO, Kolganova TV, Berestovskaya JJ, Ashikhmin AA. Lichenicoccus roseus gen. nov., sp. nov., the first bacteriochlorophyll a-containing, psychrophilic and acidophilic Acetobacteraceae bacteriobiont of lichen Cladonia species. Int J Syst Evol Microbiol. 2020 Aug;70(8):4591-4601. doi: 10.1099/ijsem.0.004318. Epub 2020 Jul 13. PMID: 32658637.

 

  1. Charles P , Kalendra V , He Z , Khatami MH , Golbeck JH , van der Est A , Lakshmi KV , Bryant DA . Two-dimensional 67Zn HYSCORE spectroscopy reveals that a Zn-bacteriochlorophyll aP' dimer is the primary donor (P840) in the type-1 reaction centers of Chloracidobacterium thermophilum. Phys Chem Chem Phys. 2020 Mar 21;22(11):6457-6467. doi: 10.1039/c9cp06556c. Epub 2020 Mar 10. PMID: 32152610.

 

  1. Hirose S, Tank M, Hara E, Tamaki H, Mori K, Takaichi S, Haruta S, Hanada S. Aquabacterium pictum sp. nov., the first aerobic bacteriochlorophyll a-containing fresh water bacterium in the genus Aquabacterium of the class Betaproteobacteria. Int J Syst Evol Microbiol. 2020 Jan;70(1):596-603. doi: 10.1099/ijsem.0.003798. PMID: 31622237.

 

  1. Meneghin E, Pedron D, Collini E. Spectroscopy data for the time and frequency characterization of vibrational coherences in bacteriochlorophyll a. Data Brief. 2019 Mar 7;23:103707. doi: 10.1016/j.dib.2019.103707. PMID: 31372380; PMCID: PMC6660430.

 

  1. Rätsep M, Linnanto JM, Freiberg A. Higher Order Vibronic Sidebands of Chlorophyll a and Bacteriochlorophyll a for Enhanced Excitation Energy Transfer and Light Harvesting. J Phys Chem B. 2019 Aug 22;123(33):7149-7156. doi: 10.1021/acs.jpcb.9b06843. Epub 2019 Aug 9. PMID: 31356081.

 

  1. Anda A, Hansen T, De Vico L. Q y and Q x Absorption Bands for Bacteriochlorophyll a Molecules from LH2 and LH3. J Phys Chem A. 2019 Jun 27;123(25):5283-5292. doi: 10.1021/acs.jpca.9b02877. Epub 2019 Jun 18. PMID: 31242736.

 

Products are for research use only. Not for human use.

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